S-Nitrosothiol

S-Nitrosothiol

A nitrosothiol is a an organic compound or functional group containing a nitroso group attached to a thiol. ["Nitroso" IUPAC nomenclature [http://www.acdlabs.com/iupac/nomenclature/79/r79_589.htm] ] The decomposition of S-nitrosothiols yields nitric oxide nitric oxide and a disulfide.

ynthesis

Nitrosothiols can be synthesized from thiols using NaNO2/H+, N2O3, N2O4, HNO, NOCl, RONO, NO2 , HNO2, bovine aortic endothelial cells, among others. NaNO2/H+ and tBuONO are commonly used. [Byler, D.M. J. Mol. Struct. 1981, 77, 25-36.] [Goto, K.; Hino, Y.; Kawashima, T.; Kaminaga, M.; Yano, E.; Yamamoto, G.; Takagi, N.; Nagase, S. Tetrahedron Letters 2000, 41, 8479-8483.] [Bartberger, M.D.; Houk, K.N.; Powell, S.C.; Mannion, J.D.; Lo, K.Y.; Stamler, J.S.; Toone, E.J. J. Am. Chem. Soc. 2000, 122, 5889-5890.] [Field, L.; Dilts, R.V.; Ravichandran, R.; Lenhert, P.G.; Carnahan, G.E. J.C.S. Chem. Comm. 1978, 249-250.]

Detection

UV-vis spectroscopy

References


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